• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
搜索

Author:

Hu, Hao (Hu, Hao.) | Liu, Yao (Liu, Yao.) | Shi, Fenglei (Shi, Fenglei.) | Tao, Peng (Tao, Peng.) | Song, Chengyi (Song, Chengyi.) | Shang, Wen (Shang, Wen.) | Ke, Xiaoxing (Ke, Xiaoxing.) | Deng, Tao (Deng, Tao.) | Zeng, Xiaoqin (Zeng, Xiaoqin.) | Wu, Jianbo (Wu, Jianbo.)

Indexed by:

EI Scopus SCIE

Abstract:

Carbon support is essential for electrocatalysis, but limitations remain, as carbon corrosion can lead to electrocatalyst degradation and affect the long-term durability of electrocatalysts. Here, we studied the corrosion dynamics of carbon nanotubes (CNTs) and Vulcan carbon (VC) together with platinum (Pt) nanoparticles in real time by liquid cell (LC) transmission electron microscopy (TEM). The results showed that CNTs with a high degree of graphitization exhibited higher corrosion resistance compared to VC. Furthermore, we observed that the main degradation path of Pt nanoparticles in Pt/CNTs was ripening, while in Pt/VC, it was aggregation and coalescence, which was dominated by the interactions between Pt nanoparticles and different hybridization of carbon supports. Finally, we performed an ex situ CV stability test to confirm the conclusions obtained from in situ experiments. This work provides deep insights into the corrosion mechanism of carbon-supported electrocatalysts to optimize the design of electrocatalysts with a higher durability.

Keyword:

Carbon corrosion Electrocatalysts Liquidcell transmission electron microscopy Metal-carboninteractions

Author Community:

  • [ 1 ] [Hu, Hao]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 2 ] [Liu, Yao]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 3 ] [Shi, Fenglei]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 4 ] [Tao, Peng]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 5 ] [Song, Chengyi]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 6 ] [Shang, Wen]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 7 ] [Deng, Tao]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 8 ] [Zeng, Xiaoqin]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 9 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China
  • [ 10 ] [Hu, Hao]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Shanghai 200240, Peoples R China
  • [ 11 ] [Shi, Fenglei]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Shanghai 200240, Peoples R China
  • [ 12 ] [Deng, Tao]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Shanghai 200240, Peoples R China
  • [ 13 ] [Ke, Xiaoxing]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 14 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Mat Genome Initiat Ctr, Shanghai 200240, Peoples R China
  • [ 15 ] [Wu, Jianbo]Shanghai Jiao Tong Univ, Zhangjiang Inst Adv Study, Future Mat Innovat Ctr, Shanghai 200240, Peoples R China

Reprint Author's Address:

  • [Zeng, Xiaoqin]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;;[Wu, Jianbo]Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;;[Ke, Xiaoxing]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China;;[Wu, Jianbo]Shanghai Jiao Tong Univ, Ctr Hydrogen Sci, Mat Genome Initiat Ctr, Shanghai 200240, Peoples R China;;[Wu, Jianbo]Shanghai Jiao Tong Univ, Zhangjiang Inst Adv Study, Future Mat Innovat Ctr, Shanghai 200240, Peoples R China

Show more details

Related Keywords:

Source :

NANO LETTERS

ISSN: 1530-6984

Year: 2024

Issue: 7

Volume: 24

Page: 2157-2164

1 0 . 8 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 8

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

Affiliated Colleges:

Online/Total:701/5423895
Address:BJUT Library(100 Pingleyuan,Chaoyang District,Beijing 100124, China Post Code:100124) Contact Us:010-67392185
Copyright:BJUT Library Technical Support:Beijing Aegean Software Co., Ltd.