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作者:

Li, Xiaoxia (Li, Xiaoxia.) | Guo, Tianqi (Guo, Tianqi.) | Shang, Yang (Shang, Yang.) | Zheng, Tian (Zheng, Tian.) | Jia, Binbin (Jia, Binbin.) | Niu, Xiaogang (Niu, Xiaogang.) | Zhu, Yujie (Zhu, Yujie.) | Wang, Zhongchang (Wang, Zhongchang.)

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摘要:

Metal hexacyanoferrates (HCFs) are viewed as promising cathode materials for potassium-ion batteries (PIBs) because of their high theoretical capacities and redox potentials. However, the development of an HCF cathode with high cycling stability and voltage retention is still impeded by the unavoidable Fe(CN)(6) vacancies (V-FeCN) and H2O in the materials. Here, we propose a repair method that significantly reduces the VFeCN content in potassium manganese hexacyanoferrate (KMHCF) enabled by the reducibility of sodium citrate and removal of ligand H2O at high temperature (KMHCF-H). The KMHCF-H obtained at 90(degrees)C contains only 2% V-FeCN, and the V-FeCN is concentrated in the lattice interior. Such an integrated Fe-CN-Mn surface structure of the KMHCF-H cathode with repaired surface V-FeCN allows preferential decomposition of potassium bis(fluorosulfonyl)imide (KFSI) in the electrolyte, which constitutes a dense anion-dominated cathode electrolyte interphase (CEI) , inhibiting effectively Mn dissolution into the electrolyte. Consequently, the KMHCF-H cathode exhibits excellent cycling performance for both half-cell (95.2 % at 0.2 Ag-1 after 2000 cycles) and full-cell (99.4 % at 0.1 Ag-1 after 200 cycles). This thermal repair method enables scalable preparation of KMHCF with a low content of vacancies, holding substantial promise for practical applications of PIBs.

关键词:

surface vacancy repairs Fe(CN)(6) vacancies K2Mn[Fe(CN)(6)] Mn dissolution potassium-ion batteries

作者机构:

  • [ 1 ] [Li, Xiaoxia]Beihang Univ, Sch Chem, Beijing 100191, Peoples R China
  • [ 2 ] [Zheng, Tian]Beihang Univ, Sch Chem, Beijing 100191, Peoples R China
  • [ 3 ] [Jia, Binbin]Beihang Univ, Sch Chem, Beijing 100191, Peoples R China
  • [ 4 ] [Niu, Xiaogang]Beihang Univ, Sch Chem, Beijing 100191, Peoples R China
  • [ 5 ] [Zhu, Yujie]Beihang Univ, Sch Chem, Beijing 100191, Peoples R China
  • [ 6 ] [Guo, Tianqi]Int Iberian Nanotechnol Lab INL, P-4715330 Braga, Portugal
  • [ 7 ] [Wang, Zhongchang]Int Iberian Nanotechnol Lab INL, P-4715330 Braga, Portugal
  • [ 8 ] [Shang, Yang]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wang, Zhongchang]Int Iberian Nanotechnol Lab INL, P-4715330 Braga, Portugal;;[Shang, Yang]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

ADVANCED MATERIALS

ISSN: 0935-9648

年份: 2024

期: 15

卷: 36

2 9 . 4 0 0

JCR@2022

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ESI高被引论文在榜: 2 展开所有

  • 2024-11
  • 2024-11

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