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Author:

Zhang, Yanli (Zhang, Yanli.) | Li, Jian (Li, Jian.) | Cai, Jianyu (Cai, Jianyu.) | Li, Shuangye (Li, Shuangye.) | Fan, Xing (Fan, Xing.) | Song, Liyun (Song, Liyun.) | Guo, Ruixue (Guo, Ruixue.) | Liu, Jiasheng (Liu, Jiasheng.)

Indexed by:

EI Scopus SCIE

Abstract:

In this study, a series of gamma-Fe2O3-modified V2O5-MoO3/TiO2 (VMT) catalysts was prepared by wet impregnation method. The gamma-Fe2O3-modified catalysts exhibited excellent catalytic performance, and 1.25 wt% gamma-Fe2O3 content improved the deNOx efficiency at 150 degrees C from 54% (unmodified VMT catalyst) to 84% (modified catalyst). BET, XRD, XPS, NH3-TPD, H2-TPR, and in situ DRIFTs were employed to characterize the physicochemical properties and reaction mechanisms of the catalysts. The introduction of gamma-Fe2O3 increased the V5+/V4+ ratio, surface chemisorbed oxygen content, redox ability, and a number of acid sites in the prepared catalysts. XPS confirmed the addition of gamma-Fe2O3 introduced new charge transfer pathways (Fe3+/Fe2+ <-> V5+/V4+). In situ DRIFTs suggested that the addition of gamma-Fe2O3 to the catalyst significantly increased the adsorption capacity of catalyst for NH3 and NOx, while also exerting a strong activating effect on the adsorbed NH3. Furthermore, selective catalytic reduction over the VMT and 5PEG@1.25Fe-VMT catalysts followed the Eley-Rideal (E-R) mechanism. At temperatures above 200 degrees C, the 5PEG@1.25Fe-VMT catalyst also followed the Langmuir-Hinshelwood (L-H) mechanism.

Keyword:

V2O5-MoO3/TiO2 NH3-SCR Low-temperature gamma-Fe2O3

Author Community:

  • [ 1 ] [Zhang, Yanli]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Jian]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 3 ] [Cai, Jianyu]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Shuangye]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 5 ] [Fan, Xing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 6 ] [Song, Liyun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Guo, Ruixue]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 8 ] [Liu, Jiasheng]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Cai, Jianyu]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;[Song, Liyun]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China;;

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Source :

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING

ISSN: 2213-2929

Year: 2024

Issue: 3

Volume: 12

7 . 7 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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