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作者:

Wu, Haihui (Wu, Haihui.) | Li, Yuqing (Li, Yuqing.) | Liu, Weiqiang (Liu, Weiqiang.) | Wang, Zhanjia (Wang, Zhanjia.) | Qin, Yuan (Qin, Yuan.) | Ji, Ming (Ji, Ming.) | Du, Ruihua (Du, Ruihua.) | Zhang, Dongtao (Zhang, Dongtao.) | Zhang, Lele (Zhang, Lele.) | Yue, Ming (Yue, Ming.) (学者:岳明) | Yi, Xiaofei (Yi, Xiaofei.) | Liu, Youhao (Liu, Youhao.) | Zha, Shanshun (Zha, Shanshun.)

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摘要:

The grain boundary diffusion (GBD) technology effectively utilizes heavy rare earth (HRE) elements to improve the coercivity of sintered Nd-Fe-B magnet. Significantly, clarifying its coercivity improvement mechanism is essential for further optimizing the process and performance. Through comparative analysis with commercial conventional magnets (CSH) processing equivalent coercivity, this study investigated the specific mechanism by which the GBD method enhances the coercivity of HRE elements in an efficient manner. To achieve the same coercivity (similar to 21.4 kOe), GBD magnets contained only 0.25 wt% Tb, whereas CSH magnets had 1.17 wt% Dy and 1.18 wt% Tb. The microstructure analysis revealed that the Tb element in the GBD magnet was concentrated in the outer layer of the grain, constituting 17.37 wt% of the total rare earth content. While, in CSH magnets, the HRE element in the main phase grains accounted for only 9.58 wt% of the total rare earth elements, including Dy (3.83 wt%) and Tb (5.75 wt%). The characteristic core-shell structural grains in GBD magnet also endowed it with an uneven magnetic domain structure and a more concentrated "abrupt" magnetization reversal. Based on the characterization results the nucleation positions of the two types of magnets were analyzed by fitting H-ci/M-s and H-a/M-s. The results can serve as a guide for enhancing coercivity in grain boundary diffusion sintered Nd-Fe-B magnets, aiding in process and property optimization, and advancing the understanding of nucleation type mechanisms.

关键词:

Sintered Nd-Fe-B magnets Grain boundary diffusion Microstructure Coercivity Domain structure

作者机构:

  • [ 1 ] [Wu, Haihui]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yuqing]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 3 ] [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 4 ] [Wang, Zhanjia]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 5 ] [Qin, Yuan]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 6 ] [Ji, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 7 ] [Du, Ruihua]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Dongtao]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 9 ] [Zhang, Lele]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 10 ] [Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China
  • [ 11 ] [Yi, Xiaofei]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 12 ] [Liu, Youhao]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 13 ] [Zha, Shanshun]State Key Lab Rare Earth Permanent Magnet Mat, Hefei 231500, Peoples R China
  • [ 14 ] [Yi, Xiaofei]Earth Panda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China
  • [ 15 ] [Liu, Youhao]Earth Panda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China
  • [ 16 ] [Zha, Shanshun]Earth Panda Adv Magnet Mat Co Ltd, Hefei 231500, Peoples R China

通讯作者信息:

  • [Liu, Weiqiang]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China;;[Yue, Ming]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Minist Educ China, Beijing 100124, Peoples R China;;

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来源 :

MATERIALS CHARACTERIZATION

ISSN: 1044-5803

年份: 2024

卷: 210

4 . 7 0 0

JCR@2022

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