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Author:

Liu, Shiqi (Liu, Shiqi.) | Wan, Jie (Wan, Jie.) | Wang, Boya (Wang, Boya.) | Li, Chenghan (Li, Chenghan.) | Wang, Yulong (Wang, Yulong.) | Wang, Lin (Wang, Lin.) | Wu, Haipeng (Wu, Haipeng.) | Zhang, Nian (Zhang, Nian.) | Zhang, Xu (Zhang, Xu.) | Yu, Haijun (Yu, Haijun.) (Scholars:尉海军)

Indexed by:

EI Scopus SCIE

Abstract:

Manganese-based lithium-rich layered oxides (Mn-LLOs) are promising candidate cathode materials for lithium-ion batteries, however, the severe voltage decay during cycling is the most concern for their practical applications. Herein, an Mn-based composite nanostructure constructed Li2MnO3 (LMO@Li2MnO3) is developed via an ultrathin amorphous functional oxide LixMnOy coating at the grain surface. Due to the thin and universal LMO amorphous surface layer etched from the lithiation process by the high-concentration alkaline solution, the structural and interfacial stability of Li2MnO3 are enhanced apparently, showing the significantly improved voltage maintenance, cycle stability, and energy density. In particular, the LMO@Li2MnO3 cathode exhibits zero voltage decay over 200 cycles. Combining with ex situ spectroscopic and microscopic techniques, the Mn2+/4+ coexisted behavior of the amorphous LMO is revealed, which enables the stable electrochemistry of Li2MnO3. This work provides new possible routes for suppressing the voltage decay of Mn-LLOs by modifying with the composite functional unit construction.

Keyword:

composite structure ultrathin amorphous coating Mn-based oxide cathode voltage decay lithium-ion battery

Author Community:

  • [ 1 ] [Liu, Shiqi]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Wan, Jie]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Wang, Boya]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Li, Chenghan]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Yulong]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Lin]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 7 ] [Wu, Haipeng]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 8 ] [Zhang, Xu]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 9 ] [Yu, Haijun]Beijing Univ Technol, Inst Adv Battery Mat & Devices, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 10 ] [Liu, Shiqi]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 11 ] [Wan, Jie]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 12 ] [Wang, Boya]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 13 ] [Li, Chenghan]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 14 ] [Wang, Yulong]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 15 ] [Wang, Lin]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 16 ] [Wu, Haipeng]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 17 ] [Zhang, Xu]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 18 ] [Yu, Haijun]Beijing Univ Technol, Key Lab Adv Funct Mat, Minist Educ, Beijing 100124, Peoples R China
  • [ 19 ] [Zhang, Nian]Chinese Acad Sci, Shanghai Inst Microsyst & Informat Technol, State Key Lab Funct Mat Informat, Shanghai 200050, Peoples R China

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Source :

SMALL

ISSN: 1613-6810

Year: 2024

Issue: 36

Volume: 20

1 3 . 3 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 3

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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