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Author:

Pan, Rui (Pan, Rui.) | Xu, Jiayi (Xu, Jiayi.) | Huang, Zhao (Huang, Zhao.) | Zhou, Taoshuai (Zhou, Taoshuai.) | Feng, Yinghao (Feng, Yinghao.) | Sun, Yihan (Sun, Yihan.) | Chen, Shujun (Chen, Shujun.) | Lin, Tiesong (Lin, Tiesong.) | He, Peng (He, Peng.)

Indexed by:

EI Scopus SCIE

Abstract:

Joint homogenization during transition metal carbides ceramic bonding has attracted much attention as a technique to increase the service temperature and relieve the residual stress for various high-temperature applications. In this work, homogeneous joints of ZrC0.85 ceramic were obtained by diffusion bonding using single Nb and multiple Ti/Nb/Ti as the interlayer. The effect of interlayer composition, bonding temperature and holding time on the microstructure of the joints was investigated. The effect of Nb and Ti on the composition homogeneity and the formation of Kirkendall voids in the ZrC0.85 joints was also discussed. When using single Nb as the interlayer, the homogenization of the joints can be achieved at a bonding temperature of similar to 1500 degrees C and holding for 1 h and no Kirkendall voids were observed when further increasing the bonding temperature to 1600 degrees C because of the good mutual solubility of NbCx and ZrCx and the relative moderate diffusion rate of Nb. However, severe Kirkendall effects were observed at a higher temperature of 1700 degrees C, which would deteriorate the high-temperature performance of the joints. The adoption of Ti/Nb/Ti further minished the diffusion rate difference of the interfacial elements through the formation of TiCx phase. As a result, only a few Kirkendall voids were formed at 1700 degrees C. Nano-hardness of the resultant homogeneous joints was comparable to that of the ZrC0.85 ceramic due to their similar composition. This study shows that active diffusion bonding based on interlayer design for homogeneous joints could pave a new way to join transition metal carbides.

Keyword:

Composite interlayer Diffusion bonding Microstructure Homogenization Transition metal carbides

Author Community:

  • [ 1 ] [Pan, Rui]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 2 ] [Xu, Jiayi]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 3 ] [Zhou, Taoshuai]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 4 ] [Feng, Yinghao]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 5 ] [Sun, Yihan]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 6 ] [Chen, Shujun]Beijing Univ Technol, Fac Mat & Mfg, Beijing 100124, Peoples R China
  • [ 7 ] [Huang, Zhao]Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Peoples R China
  • [ 8 ] [Lin, Tiesong]Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Peoples R China
  • [ 9 ] [He, Peng]Harbin Inst Technol, State Key Lab Adv Welding & Joining, Harbin 150001, Peoples R China

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Source :

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T

ISSN: 2238-7854

Year: 2024

Volume: 30

Page: 3535-3546

6 . 4 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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