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作者:

Li, Cuicui (Li, Cuicui.) | Ye, Xin (Ye, Xin.) | Jiang, Jinke (Jiang, Jinke.) | Guo, Qing (Guo, Qing.) | Zheng, Xiaoxin (Zheng, Xiaoxin.) | Lin, Qinglian (Lin, Qinglian.) | Ge, Chao (Ge, Chao.) | Wang, Shuwen (Wang, Shuwen.) | Chen, Jiashuai (Chen, Jiashuai.) | Gao, Zeliang (Gao, Zeliang.) | Zhang, Guodong (Zhang, Guodong.) | Tao, Xutang (Tao, Xutang.) | Liu, Yang (Liu, Yang.)

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EI Scopus SCIE

摘要:

The poor machinability of halide perovskite crystals severely hampered their practical applications. Here a high-throughput growth method is reported for armored perovskite single-crystal fibers (SCFs). The mold-embedded melt growth (MEG) method provides each SCF with a capillary quartz shell, thus guaranteeing their integrality when cutting and polishing. Hundreds of perovskite SCFs, exemplified by CsPbBr3, CsPbCl3, and CsPbBr2.5I0.5, with customized dimensions (inner diameters of 150-1000 mu m and length of several centimeters), are grown in one batch, with all the SCFs bearing homogeneity in shape, orientation, and optical/electronic properties. Versatile assembly protocols are proposed to directly integrate the SCFs into arrays. The assembled array detectors demonstrated low-level dark currents (< 1 nA) with negligible drift, low detection limit (< 44.84 nGy s(-1)), and high sensitivity (61147 mu C Gy(-1) cm(-2)). Moreover, the SCFs as isolated pixels are free of signal crosstalk while showing uniform X-ray photocurrents, which is in favor of high spatial resolution X-ray imaging. As both MEG and the assembly of SCFs involve none sophisticated processes limiting the scalable fabrication, the strategy is considered to meet the preconditions of high-throughput productions.

关键词:

perovskite single-crystal fibers X-ray imaging arrays high-throughput growth

作者机构:

  • [ 1 ] [Li, Cuicui]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 2 ] [Ye, Xin]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 3 ] [Jiang, Jinke]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 4 ] [Zheng, Xiaoxin]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 5 ] [Lin, Qinglian]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 6 ] [Wang, Shuwen]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 7 ] [Chen, Jiashuai]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 8 ] [Gao, Zeliang]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 9 ] [Zhang, Guodong]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 10 ] [Tao, Xutang]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 11 ] [Liu, Yang]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China
  • [ 12 ] [Guo, Qing]Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Adv Mater Div, Suzhou 215123, Peoples R China
  • [ 13 ] [Ge, Chao]Beijing Univ Technol, Inst Laser Engn, Sch Phys & Optoelect Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Ye, Xin]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China;;[Tao, Xutang]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China;;[Liu, Yang]Shandong Univ, State Key Lab Crystal Mat, 27 Shanda Nanlu, Jinan 250100, Peoples R China;;

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来源 :

SMALL

ISSN: 1613-6810

年份: 2024

期: 38

卷: 20

1 3 . 3 0 0

JCR@2022

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SCOPUS被引频次: 4

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