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作者:

Ma, Sai (Ma, Sai.) | Tang, Jiahong (Tang, Jiahong.) | Yuan, Guizhou (Yuan, Guizhou.) | Zhang, Ying (Zhang, Ying.) | Wang, Yan (Wang, Yan.) | Wu, Yuetong (Wu, Yuetong.) | Zhu, Cheng (Zhu, Cheng.) | Wang, Yimiao (Wang, Yimiao.) | Wu, Shengfang (Wu, Shengfang.) | Lu, Yue (Lu, Yue.) | Chi, Shumeng (Chi, Shumeng.) | Song, Tinglu (Song, Tinglu.) | Zhou, Huanping (Zhou, Huanping.) | Sui, Manling (Sui, Manling.) | Li, Yujing (Li, Yujing.) | Chen, Qi (Chen, Qi.)

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EI Scopus SCIE

摘要:

Enhancing the lifetime of perovskite solar cells (PSCs) is one of the essential challenges for their industrialization. Although the external encapsulation protects the perovskite device from the erosion of moisture and oxygen under various harsh conditions. However, the perovskite devices still undergo static and dynamic thermal stress during thermal and thermal cycling aging, respectively, resulting in irreversible damage to the morphology, component, and phase of stacked materials. Herein, the viscoelastic polymer polyvinyl butyral (PVB) material is designed onto the surface of perovskite films to form flexible interface encapsulation. After PVB interface encapsulation, the surface modulus of perovskite films decreases by nearly 50%, and the interface stress range under the dynamic temperature field (-40 to 85 degrees C) drops from -42.5 to 64.8 MPa to -14.8 to 5.0 MPa. Besides, PVB forms chemical interactions with FA+ cations and Pb2+, and the macroscopic residual stress is regulated and defects are reduced of the PVB encapsulated perovskite film. As a result, the optimized device's efficiency increases from 22.21% to 23.11%. Additionally, after 1500 h of thermal treatment (85 degrees C), 1000 h of damp heat test (85 degrees C & 85% RH), and 250 cycles of thermal cycling test (-40 to 85 degrees C), the devices maintain 92.6%, 85.8%, and 96.1% of their initial efficiencies, respectively. Viscoelastic PVB material is innovatively designed to form a flexible interface encapsulation. The Surface modulus and interface stress concentration zone are effectively alleviated. The stability breakthroughs in IEC 61215 (thermal treatment at 85 degrees C, damp heat test (85 degrees C & 85% RH), thermal cycling test (-40 to 85 degrees C)) has achieved through the systemic encapsulation by combining internal and external encapsulation. image

关键词:

stress field thermal shock perovskite solar cells surface modulus device stability

作者机构:

  • [ 1 ] [Ma, Sai]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 2 ] [Tang, Jiahong]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 3 ] [Yuan, Guizhou]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 4 ] [Zhang, Ying]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 5 ] [Wang, Yan]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 6 ] [Zhu, Cheng]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 7 ] [Chi, Shumeng]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 8 ] [Song, Tinglu]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 9 ] [Li, Yujing]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 10 ] [Chen, Qi]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China
  • [ 11 ] [Ma, Sai]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 12 ] [Lu, Yue]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 13 ] [Sui, Manling]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing Key Lab Microstruct & Properties Solids, Beijing 100124, Peoples R China
  • [ 14 ] [Wang, Yimiao]Jiangnan Univ, Anal & Testing Ctr, Wuxi 214122, Peoples R China
  • [ 15 ] [Wu, Shengfang]Jiangnan Univ, Anal & Testing Ctr, Wuxi 214122, Peoples R China
  • [ 16 ] [Wu, Yuetong]Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China
  • [ 17 ] [Zhou, Huanping]Peking Univ, Sch Mat Sci & Engn, Beijing 100871, Peoples R China

通讯作者信息:

  • [Li, Yujing]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China;;[Chen, Qi]Beijing Inst Technol, Sch Mat Sci & Engn, Beijing Key Lab Construct Tailorable Adv Funct Mat, MIIT Key Lab Low Dimens Quantum Struct & Devices,E, Beijing 100081, Peoples R China;;

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来源 :

ENERGY & ENVIRONMENTAL MATERIALS

年份: 2024

1 5 . 0 0 0

JCR@2022

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