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摘要:
(1-x)(0.96 Bi0.5Na0.5TiO3- 0.04BaTiO3)- xBi(Zn0.5Ti0.5)O3 ceramics were synthesized using conventional solid oxide reaction routes. The phase structure and relaxor characteristics of the ceramics were characterized by X-ray diffraction and temperature-dependence dielectric response. The results show that the perovskite structure keeps stable for Bi(Zn0.5Ti0.5)O3 addition x≤0.05.Besides, with Bi(Zn0.5Ti0.5)O3 addition increasing, the phase structure transformed from the rhombohedral- tetragonal coexistence to pseudo-cubic phase, and the diffusive factor increased while the activation energy for dipole freezing decreased. These indicate that Bi(Zn0.5Ti0.5)O3 addition significantly enhance the relaxor be-haviour of 0.96Bi0.5Na0.5TiO3- 0.04BaTiO3 ferroelectric ceramics.
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来源 :
Journal of Synthetic Crystals
ISSN: 1000-985X
年份: 2014
期: 4
卷: 43
页码: 806-810