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Author:

Zhang, Mao-Hua (Zhang, Mao-Hua.) | Zhao, Changhao (Zhao, Changhao.) | Yan, Xiaodong (Yan, Xiaodong.) | Wang, Shidong (Wang, Shidong.) | Li, Shengtao (Li, Shengtao.) | Zheng, Mupeng (Zheng, Mupeng.) | Hou, Yudong (Hou, Yudong.) | Gong, Wen (Gong, Wen.) | Chen, Long-Qing (Chen, Long-Qing.)

Indexed by:

EI Scopus SCIE

Abstract:

Grain size effects in ferroelectric ceramics have long been exploited to tailor their functional properties. However, the underlying mechanism for the grain size effects is not yet fully understood. Here, we study the grain size dependence of domain wall activities in a lead-free piezoceramics system, (Ba,Ca)(Zr,Ti)O3, with grain sizes in the range of 4 - 22 mu m. The dielectric permittivity is highest at intermediate grain sizes (-12 mu m) where there are moderate lattice distortion and the most active domain wall motion under low voltages. Despite the larger fraction of switched domains in the material with larger distortion (-22 mu m), as revealed by in situ electric -field synchrotron X-ray diffraction, time -resolved characterizations demonstrate an easier and faster domain wall dynamics in the sample with moderate lattice distortion. Our analysis and phase -field simulations show that the grain size dependence of the domain wall dynamics of polycrystalline ferroelectrics is dictated by the interaction between an external electric field and the grain size -related change in intergranular stress, and this interaction is most effective in stimulating the movement of non-180 degrees domain wall at intermediate grain sizes during the initial phase of polarization reversal. Our results provide a new fundamental understanding to guide the future design of materials for improving functionalities.

Keyword:

Lead-free electroceramics High-energy X-ray diffraction Domain wall dynamics Grain size Perovskites Phase -field simulations

Author Community:

  • [ 1 ] [Zhang, Mao-Hua]Wuzhen Lab, Jiaxing 314500, Peoples R China
  • [ 2 ] [Gong, Wen]Wuzhen Lab, Jiaxing 314500, Peoples R China
  • [ 3 ] [Zhang, Mao-Hua]Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
  • [ 4 ] [Chen, Long-Qing]Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
  • [ 5 ] [Zhang, Mao-Hua]Tech Univ Darmstadt, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany
  • [ 6 ] [Zhao, Changhao]Tech Univ Darmstadt, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany
  • [ 7 ] [Zheng, Mupeng]Tech Univ Darmstadt, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany
  • [ 8 ] [Zhao, Changhao]Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xianning West Rd 28, Xian 710049, Peoples R China
  • [ 9 ] [Li, Shengtao]Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xianning West Rd 28, Xian 710049, Peoples R China
  • [ 10 ] [Yan, Xiaodong]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 11 ] [Zheng, Mupeng]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 12 ] [Hou, Yudong]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China
  • [ 13 ] [Wang, Shidong]Peking Univ, Peoples Hosp, Musculoskeletal Tumor Ctr, Beijing 100044, Peoples R China

Reprint Author's Address:

  • [Zhao, Changhao]Tech Univ Darmstadt, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany;;[Zheng, Mupeng]Tech Univ Darmstadt, Dept Mat & Earth Sci, D-64287 Darmstadt, Germany;;[Zhao, Changhao]Xi An Jiao Tong Univ, State Key Lab Elect Insulat & Power Equipment, Xianning West Rd 28, Xian 710049, Peoples R China;;[Zheng, Mupeng]Beijing Univ Technol, Fac Mat & Mfg, Key Lab Adv Funct Mat, Educ Minist China, Beijing 100124, Peoples R China;;[Wang, Shidong]Peking Univ, Peoples Hosp, Musculoskeletal Tumor Ctr, Beijing 100044, Peoples R China;;

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Source :

ACTA MATERIALIA

ISSN: 1359-6454

Year: 2024

Volume: 276

9 . 4 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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