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The hybrid (Li, Ca)-LSX zeolites were prepared via ion exchange method with Na-LSX zeolite as starting material, and their structural and textural characteristics were investigated by using ICP-AES, TG and N2 adsorption-desorption techniques. The results showed that the order from easy to difficult for cation exchange was Ca2+, Li+, Na+. The main factors to affect the N2 adsorption ability of LSX were the size of the cation and its distribution in LSX and the binding force of cation with N2 molecules, which affected first the water absorbing capacity and textural properties, then the N2 adsorption capacity of LSX.
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