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作者:

Liu, Guohan (Liu, Guohan.) | Wei, Na (Wei, Na.) | Wu, Wenjun (Wu, Wenjun.) | Liu, Qiushan (Liu, Qiushan.) | Wang, Yufei (Wang, Yufei.) | Du, Kemeng (Du, Kemeng.) | Jia, Ruiyuan (Jia, Ruiyuan.) | Liu, Yuru (Liu, Yuru.) | Guo, Jin (Guo, Jin.) (学者:郭瑾)

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Scopus SCIE

摘要:

To control the eutrophication originating from phosphate discharge, a novel adsorptive membrane was prepared by vacuum filtrating lanthanum carbonate modified multi-walled carbon nanotubes (LC@MWCNTs) on the UF membrane. The LC@MWCNTs were firstly made using an in-situ method by adding MWCNTs to LaCl3 & sdot;7H2O solution and forming lanthanum carbonate under alkaline conditions. The adsorption experiments exhibited that the maximum adsorption capacity of LC@MWCNTs was 77.58 mg P/g at pH 5. And the phosphate adsorption by LC@MWCNTs was not predominantly reliant on electrostatic interaction, but rather achieved through chemical interactions. Then, the prepared LC@MWCNTs membrane was systematically evaluated for its phosphate removal efficiency and anti-fouling performance during filtration. With the initial phosphate concentration of 1 mg P/L and membrane flux of 378 L & sdot;m- 2 h- 1, the phosphate removal by LC@MWCNTs membrane approached almost 100 %. Moreover, the LC@MWCNTs membrane exhibited higher permeability (281.6 L & sdot;m- 2h- 1bar- 1) and effectiveness for humic acid (HA) removal (75 %), and LC@MWCNTs membrane mitigated the fouling caused by HA. XPS, FTIR and XRD elucidated that phosphate removal by LC@MWCNTs membrane primarily through the formation of La-O-P inner-sphere complexes via ligand exchange, resulting in the formation of adsorption product LaPO4 & sdot;0.5H2O. Under strong alkaline conditions, the LC@MWCNTs membrane rapidly restored its phosphate removal performance (30 min) with no significant detachment of the LC@MWCNTs layer, indicating its good recovery and reusability performance. Additionally, the LC@MWCNTs membrane could continuously remove phosphate from actual water, confirming its potential for future practical applications.

关键词:

Lanthanum carbonate Ultrafiltration Multi-walled carbon nanotubes Phosphate

作者机构:

  • [ 1 ] [Liu, Guohan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 2 ] [Wei, Na]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 3 ] [Wu, Wenjun]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 4 ] [Liu, Qiushan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Yufei]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 6 ] [Du, Kemeng]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 7 ] [Jia, Ruiyuan]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 8 ] [Liu, Yuru]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China
  • [ 9 ] [Guo, Jin]Beijing Univ Technol, Natl Engn Lab Adv Municipal Wastewater Treatment &, Ping Leyuan 100, Beijing 100124, Peoples R China

通讯作者信息:

  • [Guo, Jin]Beijing Univ Technol, 100 Pingleyuan, Beijing, Peoples R China;;

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来源 :

JOURNAL OF WATER PROCESS ENGINEERING

ISSN: 2214-7144

年份: 2024

卷: 64

7 . 0 0 0

JCR@2022

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