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Author:

Chang, Liyuan (Chang, Liyuan.) | Xia, Lingzhi (Xia, Lingzhi.) | Jiang, Qianlei (Jiang, Qianlei.) | Zhao, Wei (Zhao, Wei.) | Zhou, Kailing (Zhou, Kailing.) | Wang, Changhao (Wang, Changhao.) | Wang, Bing (Wang, Bing.) | Jin, Yuhong (Jin, Yuhong.) | Wang, Ruzhi (Wang, Ruzhi.) (Scholars:王如志)

Indexed by:

EI Scopus SCIE

Abstract:

Developing zinc-air batteries still heavily relies on the design of stable, high-activity, and inexpensive oxygen- electric bifunctional catalysts. In this work, transition metal iron salts converted amorphous carbon into graphitized carbon at high temperatures, and nitrogen-doped graphitized carbon-anchored iron nanoparticles (Fe-N-C) are prepared. Then, Fe-N-C is pyrolyzed with selenium dioxide (SeO2) 2 ) to convert iron (Fe) nano- particles into iron selenide (FeSe) in situ to obtain nitrogen-doped graphitized carbon-anchored FeSe nano- particle catalysts (FeSe/NC). The catalyst's carbon support has excellent electrical conductivity, which effectively promotes the transport rate of charges and enhances the catalytic activity of FeSe particles. FeSe/NC demonstrates outstanding catalytic activity for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER). When utilizing FeSe/NC catalysts in rechargeable zinc-air batteries (ZABs-FeSe/NC), the most excellent power density could exceed 186.6 mW cm- 2 , and the specific capacity can achieve 905.2 mAh g- 1 , demonstrating excellent performance. Furthermore, the battery can achieve stable charge-discharge for longer than 200 h at a large current density of 10 mA cm-- 2 , which has excellent practical application feasibility in the future.

Keyword:

Zinc-air batteries FeSe/NC Pyrolysis Bifunctional catalysts

Author Community:

  • [ 1 ] [Chang, Liyuan]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 2 ] [Xia, Lingzhi]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 3 ] [Jiang, Qianlei]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 4 ] [Zhou, Kailing]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 5 ] [Wang, Changhao]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 6 ] [Wang, Bing]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 7 ] [Jin, Yuhong]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 8 ] [Wang, Ruzhi]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China
  • [ 9 ] [Zhao, Wei]State Power Investment Corp Ltd, Beijing 100081, Peoples R China

Reprint Author's Address:

  • [Jin, Yuhong]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China;;[Wang, Ruzhi]Beijing Univ Technol, Inst Adv Energy Mat & Devices, Coll Mat Sci & Engn, Key Lab Adv Funct Mat Educ,Minist China, Beijing 100124, Peoples R China;;

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Source :

JOURNAL OF POWER SOURCES

ISSN: 0378-7753

Year: 2024

Volume: 620

9 . 2 0 0

JCR@2022

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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