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Author:

Lei, Kaixiang (Lei, Kaixiang.) | Zhu, Zhuo (Zhu, Zhuo.) | Yin, Zhengxuan (Yin, Zhengxuan.) | Yan, Pengfei (Yan, Pengfei.) (Scholars:闫鹏飞) | Li, Fujun (Li, Fujun.) | Chen, Jun (Chen, Jun.)

Indexed by:

Scopus SCIE

Abstract:

Mn-based oxides have attracted extensive attention as electrode materials. However, the irreversible phase transition and Mn2+ dissolution result in their structure instability and performance decay. Here, we report dual interphase layers in situ formed on P2-K0.67MnO2 (P2-KMO) in 6.0 M of potassium bis(fluorosulfonyl)amide in diglyme (KFSI/G2) during charging. It is composed of a solid-electrolyte interphase (SEI) and K-poor spinel interlayer on P2-KMO, which are derived from the simultaneous decomposition of 6.0 M KFSI/G2 and disproportionation of surface Mn3+ They cooperatively enable the reversible phase transition of P2 <-> P '' 2 in the bulk P2-KMO and mitigate Mn loss. This leads to a high capacity retention of 90.5% and a Coulombic efficiency of 100% after 300 cycles. The investigation highlights the significance of interphase chemistry of electrode materials for potassium-ion batteries and beyond.

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Author Community:

  • [ 1 ] [Lei, Kaixiang]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 2 ] [Zhu, Zhuo]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 3 ] [Yin, Zhengxuan]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 4 ] [Li, Fujun]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 5 ] [Chen, Jun]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China
  • [ 6 ] [Lei, Kaixiang]Hebei Univ Technol, Res Inst Energy Equipment Mat, Sch Mat Sci & Engn, Tianjin 300130, Peoples R China
  • [ 7 ] [Yan, Pengfei]Beijing Univ Technol, Beijing Key Lab Microstruct & Properties Solids, Inst Microstruct & Properties Adv Mat, Beijing 100124, Peoples R China

Reprint Author's Address:

  • [Li, Fujun]Nankai Univ, Key Lab Adv Energy Mat Chem, Renewable Energy Convers & Storage Ctr RECAST, Coll Chem,Minist Educ, Tianjin 300071, Peoples R China

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Source :

CHEM

ISSN: 2451-9294

Year: 2019

Issue: 12

Volume: 5

Page: 3220-3231

2 3 . 5 0 0

JCR@2022

JCR Journal Grade:1

Cited Count:

WoS CC Cited Count: 104

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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