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Abstract:
Mn-based oxides have attracted extensive attention as electrode materials. However, the irreversible phase transition and Mn2+ dissolution result in their structure instability and performance decay. Here, we report dual interphase layers in situ formed on P2-K0.67MnO2 (P2-KMO) in 6.0 M of potassium bis(fluorosulfonyl)amide in diglyme (KFSI/G2) during charging. It is composed of a solid-electrolyte interphase (SEI) and K-poor spinel interlayer on P2-KMO, which are derived from the simultaneous decomposition of 6.0 M KFSI/G2 and disproportionation of surface Mn3+ They cooperatively enable the reversible phase transition of P2 <-> P '' 2 in the bulk P2-KMO and mitigate Mn loss. This leads to a high capacity retention of 90.5% and a Coulombic efficiency of 100% after 300 cycles. The investigation highlights the significance of interphase chemistry of electrode materials for potassium-ion batteries and beyond.
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CHEM
ISSN: 2451-9294
Year: 2019
Issue: 12
Volume: 5
Page: 3220-3231
2 3 . 5 0 0
JCR@2022
JCR Journal Grade:1
Cited Count:
WoS CC Cited Count: 104
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1