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作者:

Gao, Qi (Gao, Qi.) | Ye, Qing (Ye, Qing.) (学者:叶青) | Han, Shuai (Han, Shuai.) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Kang, Tianfang (Kang, Tianfang.) (学者:康天放) | Dai, Hongxing (Dai, Hongxing.) (学者:戴洪兴)

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Scopus SCIE

摘要:

The Cu/SAPO-18 samples with different Cu/Al mass ratios were prepared, their catalytic activities for the NH3-SCR of NO in simulated diesel exhaust were evaluated, and effects of Cu/Al mass ratio and hydrothermal aging temperature on catalytic performance of Cu/SAPO-18 was examined. Physicochemical properties of the samples were characterized by means of various techniques. It is found that the activity of the sample changed with a rise in Cu/Al mass ratio, with the highest overall activity being achieved over the sample with a Cu/Al mass ratio of 0.045. The H-2-TPR results indicate that the Cu/Al mass ratio could affect the distribution of Cu species, and the Cu/SAPO-18-0.045 sample possessed the highest amount of the isolated Cu2+ species. BET and XRD results reveal that the Cu/Al mass ratio exerted little effect on the structure of the sample. Low-temperature hydrothermal treatment had the least influence on the sample, and the effect of high-temperature hydrothermal treatment on the sample became increasingly obvious with a rise in hydrothermal treatment temperature. It is concluded that the hydrothermal aging treatment mainly affected the sample by destroying the structure, blocking the pores, migration and transformation of the Cu species, and changing the acidic sites of the sample.

关键词:

Copper species Selective catalytic reduction Hydrothermal aging treatment Cu/Al mass ratio SAPO-18

作者机构:

  • [ 1 ] [Gao, Qi]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Ye, Qing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Han, Shuai]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Kang, Tianfang]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China
  • [ 7 ] [Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • 叶青 戴洪兴

    [Ye, Qing]Beijing Univ Technol, Key Lab Beijing Reg Air Pollut Control, Dept Environm Sci, Coll Environm & Energy Engn, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Beijing Key Lab Green Catalysis & Separat, Key Lab Beijing Reg Air Pollut Control, Key Lab Adv Funct Mat,Educ Minist China, Beijing 100124, Peoples R China;;[Dai, Hongxing]Beijing Univ Technol, Lab Catalysis Chem & Nanosci, Dept Chem & Chem Engn, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

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来源 :

CATALYSIS SURVEYS FROM ASIA

ISSN: 1571-1013

年份: 2019

期: 4

卷: 23

页码: 344-356

3 . 0 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:166

JCR分区:3

被引次数:

WoS核心集被引频次: 6

SCOPUS被引频次: 6

ESI高被引论文在榜: 0 展开所有

万方被引频次:

中文被引频次:

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