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In this paper, we reported a recyclable and highly active porous catalyst of titanate nanowires (TNWs) coated with well-distributed Co3O 4 nanoparticles (NPs) (Co3O4/TNWs). Sodium ions of TNWs were exchanged with hydrogen ions in the dilute nitric acid, and this protocol was very suitable for capturing cobalt ions. X-ray diffraction (XRD) demonstrated the existence of Co3O4 phase with unique lattice planes, such as (2 2 0), (3 1 1) and (5 1 1). Electron microscopes (FE-SEM and TEM) indicated that the Co3O4 NPs with an average diameter of 22 ± 3 nm were coated uniformly on TNWs surface (average diameter: 37 ± 5.5 nm), and the Co3O4 NPs mainly exposed their (2 2 0) and (2 2 2) active planes. XPS analysis confirms the formation of Co3O4 phase by the presence of Co 2p peaks at 780.1 eV (2p 3/2) and 795.5 eV (2p 1/2). Methylene blue (MB) and other organic dyes (rhodamine B (RhB) and methyl orange (MO)) were chosen as target compounds for catalytic degradation under indoor scattering light. Compared to the original Co3O4/TNWs catalyst, the catalytic efficiency of nanoscaled catalyst with oxone for MB was about 15 times higher, and the MB solution (10 mg L-1) was completely degraded within 8 min. The catalytic activity of recycled catalyst used in the sixth run still remained very active, and the degradation time for MB was only 16 min. The nanosized catalyst also had a high activity for dyes of RhB (10 mg L-1) and MO (10 mg L-1), as the degradation efficiencies of RhB and MO after 10 min of contact time were about 90.2% and 92.6%, respectively. © 2014 Elsevier Ltd.
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来源 :
Materials Research Bulletin
ISSN: 0025-5408
年份: 2014
卷: 57
页码: 170-176
5 . 4 0 0
JCR@2022
ESI学科: MATERIALS SCIENCE;
ESI高被引阀值:341
JCR分区:2
中科院分区:3