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作者:

Wei, Wei (Wei, Wei.) | Li, Yue (Li, Yue.) | Ren, Yunting (Ren, Yunting.) | Cheng, Shuiyuan (Cheng, Shuiyuan.) (学者:程水源) | Han, Lihui (Han, Lihui.)

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摘要:

Beijing as the capital of China releases massive air pollutants and experiences the worsening summer O-3 pollution recently. This study estimates Beijing ozone precursor emission, anthropogenic VOCs (AVOCs) being 325.3 kilotons in 2010, 231.8 kilotons in 2013 and 190.7 kilotons in 2015 and NOx being 211.3 kilotons in 2010, 238.3 kilotons In 2013 and 166.2 kilotons in 2015. Then, we conduct surface O-3 simulation based on WRF-Chem through using different precursor emissions, to evaluate the influence of precursor control measures on Beijing O-3. From 2010 to 2013, AVOCs reduction in Beijing would lead to O-3 decrease in urban and suburban areas and O-3 increase in some parts of northern rural areas; while from 2013 to 2015, AVOCs and NOx reductions would produce O-3 increase in urban and northern suburban areas and O-3 decrease in southern suburban and northern rural areas. Overall, the synergic reduction during 2010-2015 could effectively mitigate summer O-3 pollution over Beijing, with daily maximum 1-h ozone (DAM1h O-3) reduction exceeding 3 ppb. Finally, based on 2015 emission condition, 30% NOx and 30% VOCs emission reduction are further simulated to study O-3-NOx-VOCs sensitivity over Beijing. The simulated DAM1h O-3 reduction due to NOx- or VOCs-reduction shows that O-3 is predominantly sensitive to VOCs in urban and northern suburban Beijing, but seems to be control more by the mixed chemistry in southern suburban and northern rural Beijing. However, NOx-sensitive condition is never found in rural Beijing. The distribution of simulated H2O2/HNO3 for the distinguished VOCs- and NOx-sensitive grids shows that 95th percentile for VOCs-sensitive distribution and 5th percentile for the NOx-sensitive distribution are 2.48 and 1.17 in all simulated days. According to the determined transition values, most Beijing is under VOCs-sensitive regime on the condition of 2015 precursor emission.

关键词:

Precursor emission change WRF-Chem simulation Surface ozone Sensitivity

作者机构:

  • [ 1 ] [Wei, Wei]Beijing Univ Technol, Dept Environm Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Li, Yue]Beijing Univ Technol, Dept Environm Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Ren, Yunting]Beijing Univ Technol, Dept Environm Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Cheng, Shuiyuan]Beijing Univ Technol, Dept Environm Sci & Engn, Beijing 100124, Peoples R China
  • [ 5 ] [Han, Lihui]Beijing Univ Technol, Dept Environm Sci & Engn, Beijing 100124, Peoples R China
  • [ 6 ] [Wei, Wei]Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 7 ] [Cheng, Shuiyuan]Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China
  • [ 8 ] [Han, Lihui]Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

通讯作者信息:

  • [Wei, Wei]Key Lab Beijing Reg Air Pollut Control, Beijing 100124, Peoples R China

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来源 :

ATMOSPHERIC ENVIRONMENT

ISSN: 1352-2310

年份: 2019

卷: 218

5 . 0 0 0

JCR@2022

ESI学科: GEOSCIENCES;

ESI高被引阀值:123

JCR分区:2

被引次数:

WoS核心集被引频次: 33

SCOPUS被引频次: 38

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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