Graphene　has　attracted　widely　attention　due　to　its　good　electrical　conductivity,　high　specific　surface　area　and　good　biocompatibility.　The　graphene　with　specific　surface　area　of　535　m2/g　was　obtained　by　using　chemical　reduction　method.　In　the　present　study,　the　graphene　modified　carbon　cloth　(GNS-anode)　was　used　as　a　microbial　fuel　cell　anode　and　compare　the　perormonce　with　multi-walled　carbon　nanotubes　modified　carbon　cloth　(MWCNT-anode)　and　carbon　cloth　(CC-anode).　With　GNS-anode,　the　microbial　fuel　cell　yields　a　maximum　power　density　of　652　mW/m2,　which　is　1.4　times　and　2.2　times　larger　than　that　of　the　MFC　with　MWCNT-anode　and　CC-anode　respectively.　The　great　improvement　is　attributed　to　the　fact　that　the　graphene　has　high　specific　surface　area,　high　electrical　conductivity　and　good　biocompatibility.　The　electrodes　are　characterized　by　scanning　electron　microscopy　(SEM),　Brunauer　Emmett　Teller　(BET),　transmission　electron　microscope　(TEM)　and　X-ray　diffraction　(XRD).　The　electrochemical　properties　have　been　investigated　by　cyclic　voltammetry　(CV)　and　electrochemical　impedance　spectroscopy　(EIS).