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AlN buffer and GaN epitaxial layer were prepared by MOCVD on Si(111) substrate. The effect of H2 carrier gas flow for AlN buffer epitaxy on GaN was investigated by high resolution X-ray diffraction, ellipsometer and atomic force microscope. It is found that AlN thickness increases (i.e. the increasing of AlN growth rate) with the increasing of H2 flow. The surface roughness of AlN also tends to increase. The change in surface roughness is attributed to the enhancement of island-growth mode. The increasing of AlN buffer thickness contributes to the increasing of tensile stress which promotes AlN island growth mode. The higher density of islands with bad orientation was observed by AFM on AlN buffer layer which was grown with higher H2 flow. ω scan of (0002) and (101¯2) show that the increasing of H2 flow leads to the increasing in FWHM of GaN(i.e. the increasing in density of screw threading dislocation and edge threading dislocation). Because the three-dimensional growth of GaN starts on the top of AlN islands, the AlN buffer layer with high density of islands contributes to rapid coalescence of GaN islands that will lead high density of edge threading dislocation. The bad orientation of AlN islands on buffer layer will lead to GaN thin film with high density of screw threading dislocation. The obtained data demonstrate that the H2 carrier gas flow plays an important role in improving the crystal quality of GaN.
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