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摘要:
Pr3+, Yb3+ co-doped YPO4 downconversion phosphor powders were prepared by solid state reaction. When excitation at 450 nm, the effects of different Yb3+ mole fractions (0%, 1%, 2%, 4%, 20%, 30%) on the conversion efficiency are studied. Results shows that because of the difference of energy transfer efficiency between Pr3+ and Yb3+, the samples with various Yb3+ doping concentrations have different fluorescence intensity. It is also found that the energy transfer process of the downconversion luminescence in samples is Pr3+: 3P0→Yb3+: 2F5/2+2F5/2. From photoluminescence spectra measurement, the optimal doping mole fraction of Yb3+ is 2%. The results indicate that Pr3+, Yb3+ co-doped YPO4 downconversion phosphor is a kind of potential material which may be used to improve the solar cell efficiency.
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