The　catalytic　performances　of　metalloporphyrins　and　compounding　catalytic　systems　in　the　aerobic　oxidation　of　4-nitroethylbenzene　to　4-nitroacetophenone　is　comprehensively　investigated　with　a　solvent-free　system　at　atmospheric　pressure.　It　is　found　that　all　of　the　metalloporphyrins　or　compounding　catalytic　systems　have　catalytic　performances,　and　the　catalytic　performances　of　different　metalloporphyrins　or　compounding　catalytic　systems　are　obviously　diverse.　Meanwhile,　the　cooperation　of　metalloporphyrins　and　transition　metallic　salts　in　the　above　reactions　is　acquired　because　the　catalytic　effects　of　the　compounding　catalytic　systems　are　better　than　the　metalloporphyrins　as　single　catalyst.　Compared　the　oxidation　of　4-nitroethylbenzene　catalyzed　by　T　(p-OCH3)PPMnCl-cobalt　stearate　as　the　best　compounding　catalytic　system　with　the　reaction　without　catalysts　(blank　reaction),　the　initiation　temperature　decreases　from　190　°C　to　155　°C,　while　the　conversion　of　4-nitroethylbenze　increases　from　11.3%　to　61.5%,　the　selectivity　for　4-nitroacetophenone　increases　from　52.5%　to　88.9%,　and　the　yield　of　4-nitroacetophenone　increases　from　5.9%　to　54.7%.