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The silicon thin films were prepared with different substrate temperatures and different hydrogen dilution ratios by using HWAMWECR-CVD method. The phase transition process from amorphous to microcrystalline silicon and photo-electronic properties were studied. The experimental results showed that when the silicon thin films were prepared at low temperatures, both of improving the substrate temperature and hydrogen dilution ratio played important roles, but the influence of hydrogen dilution ratio was more obvious than that of substrate temperature; higher microcrystalline volume fraction didn't represent higher photo-electronic properties. In the experiment, high-quality μc-Si:H thin films were prepared at 95% hydrogen dilution ratio.
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