With　the　development　of　high-performance　steel　(HPS)　in　the　modern　steel　structures,　the　basic　members　of　prestressed　steel　structures,　i.　e.　the　prestressed　stayed　column　will　have　a　significant　influence　on　the　overall　stability　behavior.　The　elastic　buckling　analysis　of　ordinary　steel　material　prestressed　stayed　column　and　ordinary　column　were　studied　with　the　finite　element　analysis　software　ANSYS.　The　finite　element　model　was　verified　by　comparison　with　the　theoretical　results.　Then　the　non-linear　buckling　analysis　considering　material　nonlinearity,　geometric　nonlinearity　and　the　initial　imperfection　was　conducted　to　compare　the　influence　of　the　steel　material　type　on　the　overall　stability　behavior　of　prestressed　stayed　column　and　ordinary　column.　The　results　show　that　with　the　use　of　prestressed　stayed　system　and　HPS,　the　stability　load-carrying　behavior　of　axial　compression　column　are　improved　substantially.