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作者:

Yuan, Huiping (Yuan, Huiping.) | Zhang, Teng (Zhang, Teng.) | Suo, Hongli (Suo, Hongli.) (学者:索红莉) | Wang, Zhao (Wang, Zhao.) | Cheng, Yanling (Cheng, Yanling.)

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摘要:

Thermogravimetric analysis was used to study the thermal decomposition kinetics of the thermotropic liquid crystalline polyamide at different heating rates in streams of N2 and air. The mechanism function was identified with the kinetic parameters obtained from the analysis of TG-DTG curves by the Friedman method, the Kissinger method, the Ozawa method and the Coats-Redfern method. The most probable kinetic function of the thermal decomposition in N2 was Avrami-Erofeev theorem. The activation energy is 208 kJ/mol. The most probable kinetic function of the thermal decomposition in air of the first stages was Mempel Power theorem. The activation energy is 172 kJ/mol. The most probable kinetic function of the thermal decomposition in air of the second stages was reverse Jander theorem. The activation energy is 111 kJ/mol. The lifetime at weight-loss of 5% at different temperature was deduced by isothermal TG analysis.

关键词:

Activation energy Crystalline materials Decomposition Degradation Enzyme kinetics Kinetics Liquids Pyrolysis Thermogravimetric analysis Thermolysis

作者机构:

  • [ 1 ] [Yuan, Huiping]Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Zhang, Teng]Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 3 ] [Suo, Hongli]Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 4 ] [Wang, Zhao]Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 5 ] [Cheng, Yanling]Key Laboratory of Advanced Functional Materials, College of Material Science and Engineering, Beijing University of Technology, Beijing 100124, China

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来源 :

Polymeric Materials Science and Engineering

ISSN: 1000-7555

年份: 2011

期: 4

卷: 27

页码: 32-36

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