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CO2 dilution is an effective strategy for combustion control. To understand the detailed dilution effects of CO2 (including physical effects and chemical effects) on CH4 and H-2 combustion, an open-source CFD package laminarSMOKE was utilized to simulate the transient one-dimensional outwardly spherical flame combustion process in a closed chamber under 0-15% CO2 dilution mole fraction (alpha), at 293 K, 1 bar, stoichiometric ratio. The overall CO2 dilution effects decrease the unstretched/stretched flame propagation speed, maximum combustion pressure and prolong the combustion duration. In most conditions, physical effects play a dominant role and chemical effects amplify the dilution effects. Typically, the maximum combustion pressure of CH4-CO2-air flame at alpha = 15% reduces 1.15 bar compared with the undiluted case, the reduction percentage caused by physical and chemical effects is 12% and 1.5%, respectively. In addition, opposite overall effects of CO2 dilution on Markstein length (L-b) of CH4 flames and H-2 flame are performed. The physical effects of CO2 dilution increase the L-b of CH4 flames but decrease that of H-2 flames. Chemical effects are similar to physical effects for CH4 flames, but nonmonotonic behavior is performed for H-2 flame due to the combined effects of density ratio and mixture reactivity changes. (C) 2019 Elsevier Ltd. All rights reserved.
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