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作者:

Huang, Kelin (Huang, Kelin.) | Wu, Rui (Wu, Rui.) | Li, Huiquan (Li, Huiquan.) | Cao, Yan (Cao, Yan.) | Wang, Jinshu (Wang, Jinshu.) (学者:王金淑)

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EI Scopus PKU CSCD

摘要:

Using ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl)as reaction media, microcrystalline cellulose as raw material, the kinetics of homogeneous acylation of cellulose in ionic liquid was studied. The effect of initial cellulose hydroxyl concentration from 0.21 mol·L-1 to 0.85 mol·L-1 and temperatures from 353 K to 373 K on the acylation rate were measured. Results showed that the acylation rate increases with increasing initial cellulose hydroxyl concentration and reaction temperatures. The reaction kinetic equations were determined based on the experimental data. The reaction order for both acylation by acetic anhydride and by mixture of butyric anhydride and acetic anhydride is first-order, and their apparent activation energies are 19.03 kJ·mol-1 and 20.04 kJ·mol-1 respectively. © All Rights Reserved.

关键词:

Activation energy Acylation Cellulose Chlorine compounds Enzyme kinetics Integral equations Ionic liquids Kinetics Reaction kinetics

作者机构:

  • [ 1 ] [Huang, Kelin]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
  • [ 2 ] [Huang, Kelin]Guangxi Branch of China Academy of Science and Technology Development, Nanning 530022, Guangxi, China
  • [ 3 ] [Huang, Kelin]Guangxi Research Institute of Chemical Industry, Nanning 530001, Guangxi, China
  • [ 4 ] [Wu, Rui]Chemistry and Ecological Engineering College, Guangxi University for Nationalities, Nanning 530006, China
  • [ 5 ] [Li, Huiquan]Institute of Process Engineering, Chinese Acad. of Sci., Beijing 100190, China
  • [ 6 ] [Cao, Yan]Institute of Process Engineering, Chinese Acad. of Sci., Beijing 100190, China
  • [ 7 ] [Wang, Jinshu]College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China

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来源 :

CIESC Journal

ISSN: 0438-1157

年份: 2011

期: 7

卷: 62

页码: 1898-1905

被引次数:

WoS核心集被引频次: 0

SCOPUS被引频次: 1

ESI高被引论文在榜: 0 展开所有

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