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Using ionic liquid 1-allyl-3-methylimidazolium chloride (AmimCl)as reaction media, microcrystalline cellulose as raw material, the kinetics of homogeneous acylation of cellulose in ionic liquid was studied. The effect of initial cellulose hydroxyl concentration from 0.21 mol·L-1 to 0.85 mol·L-1 and temperatures from 353 K to 373 K on the acylation rate were measured. Results showed that the acylation rate increases with increasing initial cellulose hydroxyl concentration and reaction temperatures. The reaction kinetic equations were determined based on the experimental data. The reaction order for both acylation by acetic anhydride and by mixture of butyric anhydride and acetic anhydride is first-order, and their apparent activation energies are 19.03 kJ·mol-1 and 20.04 kJ·mol-1 respectively. © All Rights Reserved.
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来源 :
CIESC Journal
ISSN: 0438-1157
年份: 2011
期: 7
卷: 62
页码: 1898-1905