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作者:

Jiang, Yang-ye (Jiang, Yang-ye.) | Dou, Gui-yuan (Dou, Gui-yuan.) | Zhang, Luo-sha (Zhang, Luo-sha.) | Xu, Kun (Xu, Kun.) | Little, R. Daniel (Little, R. Daniel.) | Zeng, Cheng-chu (Zeng, Cheng-chu.) (学者:曾程初)

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Scopus SCIE

摘要:

Photoredox-based C-H bond functionalization constitutes one of the most powerful and atom-economical approaches to organic syntheses. During this type of reaction, single electron transfer takes place between the photocatalyst (PC) and redox- active substrates. Electrosynthesis also involves electron transfer between substrates and electrodes. In this paper, we focus upon electrochemical cross-coupling of C(sp(2))-H with aryldiazonium salts and have developed an efficient electrochemical approach to the Minisci-type arylation reaction. The constant current paired electrosynthesis proceeds in a simple undivided cell without external supporting electrolyte, features a wide range of substrates and is easy to scale-up. These results demonstrate that photoredox-based cross-coupling of C(sp(2))-H with aryldiazonium salts can also proceed successfully under paired electrolysis conditions, thereby contributing to understanding of the parallels between photosynthesis and electrosynthesis.

关键词:

photoredox-based reactions cross-coupling paired electrolysis aryldiazonium salts quinoxalin-2(1H)-ones

作者机构:

  • [ 1 ] [Jiang, Yang-ye]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 2 ] [Dou, Gui-yuan]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 3 ] [Zhang, Luo-sha]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 4 ] [Xu, Kun]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 5 ] [Zeng, Cheng-chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China
  • [ 6 ] [Little, R. Daniel]Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

通讯作者信息:

  • 曾程初

    [Zeng, Cheng-chu]Beijing Univ Technol, Coll Life Sci & Bioengn, Beijing Key Lab Environm & Viral Oncol, Beijing 100124, Peoples R China

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来源 :

ADVANCED SYNTHESIS & CATALYSIS

ISSN: 1615-4150

年份: 2019

期: 22

卷: 361

页码: 5170-5175

5 . 4 0 0

JCR@2022

ESI学科: CHEMISTRY;

ESI高被引阀值:166

JCR分区:1

被引次数:

WoS核心集被引频次: 72

SCOPUS被引频次: 74

ESI高被引论文在榜: 0 展开所有

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