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According to the Sellmeier dispersion equation and law of energy conservation and momentum conservation, the tuning characteristics, conversion efficiency, permitted parametric and walk-off effect of ZGP-DFG have been obtained using numerical simulation in type-I and type-II phase-matched. The ranges of angle tuning were 51°~89° in type-I, and 58°~88° in type-II. The corresponding ranges of wavelength were 3.1~12 μm and 6.2~11.5 μm, respectively. In addition, the corresponding characteristics of AgGaS2 (AGS) and AgGaSe2 (AGSe) were compared with ZGP, and the conclusion was the walk-off effect of ZGP-DFG was small, and the conversion efficiency of ZGP-DFG was the highest among the three crystals. In summary, ZGP was a better crystal to produce the mid-infrared laser.
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