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摘要：
Symmetrical bisamides of ethylene diamine of type ArCONHCH2CH2NHCOAr undergo anodic C-C bond cleavage in acetonitrile-LiClO4 under controlled-potential electrolysis. The electrogenerated carbocation intermediates react with the solvent acetonitrile to afford unsymmetrical gem-bisamides of type ArCONHCH2NHCOMe in a one-pot reaction. The yields of the latter products are moderate (up to 60%). Other minor products involve two symmetrical gem-bisamides of type ArCONHCH2NHCOAr and MeCONHCH2NHCOMe and fragmentation products (e.g., ArCONHCHO, ArCONH2, and ArCN).
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来源 ：
ORGANIC LETTERS
ISSN： 1523-7060
年份： 2019
期： 19
卷： 21
页码： 7961-7964
5 . 2 0 0
JCR@2022
ESI学科： CHEMISTRY;
ESI高被引阀值：166
JCR分区：1
