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摘要:
The bulk nanocrystalline SmCo5 sintered magnet was prepared by spark plasma sintering technique (SPS). The structure and magnetic properties of the magnet were studied. XRD patterns show that the mill powder exhibits amorphous structure and the magnet exhibits CaCu5 structure. TEM observation indicates that the microstructure of the magnet is composed of SmCo5 single phase grains with an average grain size of 30 nm. The magnetic measurement shows that the coercivity of the magnet reaches as high as 2.28 MA/m. The high ratio Mr/Ms of 0.7 demonstrates the existence of strong intergrain exchange coupling among the nanograins. The magnet exhibits a good thermal stability with coercivity of 0.72 MA/m at 773 K, and the coercivity temperature coefficient β of -0.146%/K.
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来源 :
Chinese Journal of Nonferrous Metals
ISSN: 1004-0609
年份: 2009
期: 7
卷: 19
页码: 1305-1309