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To investigate the occurrence and characteristics of denitrifying phosphorus removal, a lab-scale A2O reactor with working volume of 52.5 L was employed to treat municipal wastewater. The effects of influent COD/TN ratio and the volume ratio of anoxic zone to aerobic zone on denitrifying phosphorus removal were studied. Results show that 36% of total soluble phosphorus can be removed in the anoxic reactor when the HRT is 8 h, sludge recycle ratio is 70% and internal recycle ratio is 250%. Results of batch experiment show that more than 35.4% of phosphorus accumulating organisms (PAOs) in the A2O system can be denitrified. The ratio of anoxic phosphorus uptake increases with the decrease of influent COD/TN ratio. Denitrifying phosphorus removal can also be enhanced by increasing the ratio of anoxic zone to aerobic zone from 1/1 to 5/8. Meanwhile, the TN removal efficiency is increased from 62% to 70%. It is a more energy-efficient way compared with the increase of internal recycle ratio, which can increase the ratio of anoxic phosphorus uptake. Enhancing the denitrifying phosphorus removal in A2O process is an effective way to enhance biological nutrient removal in treating municipal wastewater with low C/N ratio.
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