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Simultaneously involving abundant [NH2(CH3)(2)](+) cations and uncoordinated carboxylate oxygen atoms as dual active sites, two microporous Co-II-MOFs (LCU-105 and LCU-106, LCU = Liaocheng University) both exhibit highly selective adsorption of CO2/CH4 and CO2/N-2. GCMC theoretical simulations provide good verification of the experimental results.
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