Non-thermal　plasma　technology　is　currently　facing　two　bottleneck　problems-energy　consumption　and　byproducts　control.　For　resolving　these　two　problems,　a　series　of　experiments　using　non-thermal　plasma　technology　coupled　with　adsorption　and　catalysis　for　toluene　removal　was　carried　out.　Our　aim　is　to　resolve　these　two　problems.　In　the　experiment,　the　corresponding　electric　field　strength,　energy　density,　removal　efficiency,　energy　efficiency,　ozone　production　rates　and　other　reaction　parameters,　such　as　by-products,　were　studied　with　different　packed　materials　in　the　plasma　reactor.　The　results　show　the　synergistic　technology　resulted　in　greater　enhancement　of　toluene　removal　efficiency　(up　to　98.7%)　and　energy　efficiency　and　a　better　inhibition　for　O3　and　the　other　byproducts　formation　in　the　gas　exhaust.