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作者:

Zhang, Yan (Zhang, Yan.) | Kang, Tian-Fang (Kang, Tian-Fang.) (学者:康天放) | Hao, Yu-Cui (Hao, Yu-Cui.) | Yin, Hong-Xia (Yin, Hong-Xia.)

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摘要:

Platinum particles were electrochemically deposited on glassy carbon electrodes modified by carbon nanotubes. The chemically modified glassy carbon electrodes with platinum particles and carbon nanotubes (Pt/CNTs/GCE) were used as formaldehyde sensors. Electrochemica1 behaviors of formaldehyde at Pt/CNTs/GCE were investigated by cyclic voltammetry (CV) and linear scan voltammetry (LSV). Experimental conditions were optimized, and a voltammetric method for determining formaldehyde was developed. The experimental results show that the optimum accumulation potential is -0.1 V and the optimum accumulation time is 180 s. A highly linear response to formaldehyde in the concentration range of 8.0mol/L-1.0 mmol/L was observed in 0.01 mol/LH2SO4, with a detection limit of 3.0mol/L estimated at a signal-to-noise ratio of 3:1. The presented method of determining formaldehyde exhibits high sensitivity and good reproducibility.

关键词:

Glass membrane electrodes Carbon nanotubes Platinum compounds Formaldehyde Platinum Glass Signal to noise ratio Cyclic voltammetry

作者机构:

  • [ 1 ] [Zhang, Yan]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, China
  • [ 2 ] [Kang, Tian-Fang]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, China
  • [ 3 ] [Hao, Yu-Cui]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, China
  • [ 4 ] [Yin, Hong-Xia]College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100022, China

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来源 :

Journal of Beijing University of Technology

ISSN: 0254-0037

年份: 2008

期: 11

卷: 34

页码: 1191-1195

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