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TiB2-316L stainless steel matrix composite powders contained 10mass% and 40mass% TiB2 were prepared by high energy ball milling and spray-drying processes respectively. Atmospheric plasma spraying deposited corresponding coatings and 316 L stainless steel coating. High velocity block-on-ring wear tester was used to test wear resistance of as-sprayed coatings. X-ray diffraction analyzed the constitution of as-sprayed coatings. Scanning electron microscope was employed to character as-sprayed coatings, feedstocks and the worn surface morphology. Results show that wear resistance of as-sprayed TiB2-316L stainless steel matrix composite coatings is prior to 316L stainless steel coating. TiB2 particles act as reinforcement component in the coating and oxides from tribo-oxidation of TiB2 in the tribo contact, which possessed self-lubricating function, can reduce mass loss of the coatings during sliding wear.
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