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In order to study the effect of nitrate on the biological phosphorus removal, the anaerobic-anoxic-aerobic (A2/O) oxidation ditch (OD) process was adopted to treat the municipal wastewater combined with the captive test for 4 months, meanwhile the operation data of an A2/O oxidation ditch wastewater treatment plant were analyzed. The effect of nitrate on phosphorus release in the anaerobic zone and in the secondary clarifier was studied. The volume of the whole reactor was 375 L. The result indicated that with the effluent NO3-of the OD more than 5.0 mg/L, the phosphorus release was restrained by NO3-carried by the returned activated sludge, resulting in the decrease of TP removal rate with the increase of NO3-in the effluent. When NO3-in the effluent was less than 5.0 mg/L, the TP removal rate was decreased with the decrease of NO3-in the effluent due to the phosphorus release happened in the low NO3-condition with inner carbon resource acting as an electronic acceptor. The captive test indicated that the phosphorus release with inner carbon resource acting as the electronic acceptor was restrained when NO3-was more than 0.5 mg/L in the secondary clarifier, while phosphorus was released with the inner carbon being the electronic acceptor when NO3-was less than .5 mg/L, and the specific phosphorus release rate was 0.18-0.47 mg/(gVSS · h). The operation result of the wastewater treatment plant indicated that retention time of the activated sludge in the secondary clarifier was so long that it would increase the effluent TP due to the phosphorus release with inner carbon resource.
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