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作者:

Zhao, Xinran (Zhao, Xinran.) | He, Xiaobo (He, Xiaobo.) | Chen, Biaohua (Chen, Biaohua.) (学者:陈标华) | Yin, Fengxiang (Yin, Fengxiang.) | Li, Guoru (Li, Guoru.)

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EI Scopus SCIE

摘要:

In this work, a series of metallic Co-ZnO encapsulated in N-doped carbon/carbon nanotubes (Co-ZnO@NC/CNT-T) for the electrochemical oxygen reduction reaction (ORR) were synthesized by annealing bimetallic metal-organic frameworks (MOFs) containing Co and Zn in N-2 atmosphere. Within the hybrid, metallic Co was integrated with ZnO and encapsulated by NC, while coral-like CNTs grew out of the obtained Co-ZnO@NC nanoparticles. When applied in ORR catalysis, the optimized Co-ZnO@NC/CNT-700 obtained in 700 degrees C displayed a half-wave potential of similar to 0.86 V and a limiting current density of similar to-5.98 mA cm(-2), which were even superior to 20 wt% Pt/C. Further results demonstrated that the presence of ZnO was closely related with the high ORR catalytic activity from two aspects. (i) ZnO catalyzed the formation of Co-0, Co2+, pyridinic and graphitic N as the main active species for ORR. (ii) ZnO promoted the growth of CNTs and micro/mesoporous structure, which improved the electrochemical active surface area (ECSA) and mass transfer during the ORR process.

关键词:

Carbon nanotubes Oxygen reduction reaction N-doped carbon Zinc oxide Metallic cobalt

作者机构:

  • [ 1 ] [Chen, Biaohua]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China
  • [ 2 ] [He, Xiaobo]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 3 ] [Yin, Fengxiang]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 4 ] [Li, Guoru]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China
  • [ 5 ] [Zhao, Xinran]Beijing Univ Chem Technol, Coll Chem Engn, Beijing 100029, Peoples R China
  • [ 6 ] [He, Xiaobo]Beijing Univ Chem Technol, Changzhou Inst Adv Mat, Changzhou 213164, Peoples R China
  • [ 7 ] [Yin, Fengxiang]Beijing Univ Chem Technol, Changzhou Inst Adv Mat, Changzhou 213164, Peoples R China

通讯作者信息:

  • 陈标华

    [Chen, Biaohua]Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China;;[Yin, Fengxiang]Changzhou Univ, Sch Petrochem Engn, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

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来源 :

APPLIED SURFACE SCIENCE

ISSN: 0169-4332

年份: 2019

卷: 487

页码: 1049-1057

6 . 7 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:211

JCR分区:1

被引次数:

WoS核心集被引频次: 27

SCOPUS被引频次: 30

ESI高被引论文在榜: 0 展开所有

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中文被引频次:

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