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The nonstoichiometric CuxAlO2 ceramics were successfully prepared by solid state sintering at high temperature. The effects of the x value on the band gap and electrical conductivity were investigated. The results show that the structure and density of CuxAlO2 ceramic plates show a notable improvement with the increasing content of Cu. The maximum value of density is 5.02 g/cm3 for CuxAlO2 ceramic with x=0.98 and the XRD pattern indicates that it is a pure CuA1O2 phase. The optical band gap of CuxA1O2 ceramics is about 3.44 eV. The conductivity at room temperature increases first and then reduces with the increasing content of Cu. The maximum conductivity is about 8.03 × 10-3 S/cm with x=0.98. The temperature dependence of electrical conductivity agrees well with the Arrhenius relationship, indicating that the electrical conducting is ascribed to thermal activation in the range of 100-300 K. The minimal value of the activation energy is estimated 0.085 eV. The electrical conductivity of CuxAlO2 ceramics mainly depends on the density of the samples in the investigating range.
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