Constructing　Z-scheme　type　photocatalysts　is　preferred　to　achieve　efficient　photocatalyst　owing　to　the　high　oxidative　and　reductive　capabilities　of　composite　catalysts.　The　direct　Z-scheme　(DZS)　is　composed　of　two　semiconductors　contacting　each　other,　which　eliminates　the　disadvantages　of　using　an　electron　mediator　in　liquid　and　solid-state　Z-schemes.　However,　deliberately　constructing　a　DZS　remains　challenging.　In　this　report,　two　semiconductors　were　denoted　as　SC-I　and　SC-II　according　to　the　natural　photosynthesis　process.　Two　routes　for　constructing　DZS　catalysts　through　photodeposition　were　demonstrated,　which　effectively　regulated　the　photogenerated　charge　transfer　direction.　Starting　from　SC-I,　SC-II　was　selectively　deposited　at　the　hole-rich　site　of　SC-I　by　photooxidation.　Starting　from　SC-II,　SC-I　was　selectively　grown　at　the　electron-rich　site　of　SC-II　through　photoreduction.　This　selective　deposition　promoted　directional　charge　recombination　to　form　DZS　catalysts.　Two　examples,　Fe2O3/g-C3N4　and　CdS/TiO2,　were　synthesized　by　photooxidation　and　photoreduction,　respectively.　Charge-transfer　tracking　and　reactive　oxygen　species　were　used　to　check　the　charge　transfer　direction　and　radical　type.　The　results　showed　that　both　systems　indeed　formed　DZS　catalysts.　Based　on　the　above　results,　photodeposition　can　be　used　to　deliberately　construct　DZS　catalysts.