Ti/SnO2-Sb　electrode　was　widely　used　in　wastewater　treatment　due　to　its　less　toxic　and　high　oxidation　activity.　Unfortunately,　it　also　exhibited　shortcomings　such　as　high　energy　consumption　and　instability.　Herein,　Cu　doping　TiO2/SnO2-Sb　electrode　was　prepared　by　sol-gel　and　anodic　oxidation.　The　addition　of　TiO2　could　reduce　the　internal　passivation　of　the　electrode　and　the　charge　transfer　resistance　(R-ct)　from　158　Omega　to　86.42　Omega,　reinforce　its　stability　and　oxidation　efficiency.　Cu　was　used　to　limit　the　growth　of　crack　morphology　and　provide　more　effective　active　sites　which　increasing　the　adsorbed　oxygen　from　49.67%　to　55.00%.　They　accelerated　electronic　transfer　and　reduced　the　surface　potential　of　SnO2　respectively,　improve　the　oxygen　evolution　potential　(OEP)　from　2.0　V　to　2.7　V　and　increase　the　response　current　peak　from　25.86　mA　to　48.66　mA,　which　enhanced　the　oxidative　degradation　ability　of　the　electrode.　The　degradation　efficiency　of　ceftazidime　by　Ti/TiO2/SnO2-Sb-Cu　was　97.65%　and　81.87%　after　20　consecutive　cycles　of　use,　which　was　much　higher　than　51.58%　of　Ti/SnO2-Sb.　The　experiment　also　optimized　parameters　such　as　current　density,　supporting　electrolyte　concentration,　electrode　spacing　and　pH.　Finally,　the　possible　degradation　pathways　and　intermediates　of　ceftazidime　were　inferred　by　LC-MS.