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Sprayable feedstocks were prepared by spray-drying and using alumina-30% titanium diboride composite powder mixed with 10% nanoscale alumina powder with a particle size of 80-200 nm, and a titanium diboride-alumina composite coating was deposited by axial-III plasma spraying system. The coating constitution and microstructure were analyzed by X-ray diffraction, scanning electron microcopy. Microhardness and Rockwell Hardness were tested on the surface of the coating. Results show that the coating consists of α-alumina, γ-alumina, titanium diboride and a small amount of titania; titanium diboride is mostly presented with particles in the coatings. The average superficial Rockwell hardness of as-sprayed coating is 52.9, microhardness of TiB2 is 16.68 GPa.
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