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作者:

Saddique, Jaffer (Saddique, Jaffer.) | Cheng, Xiaopeng (Cheng, Xiaopeng.) | Shi, Huifeng (Shi, Huifeng.) | Wu, Rui (Wu, Rui.) | Zhang, Yuefei (Zhang, Yuefei.) (学者:张跃飞)

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Scopus SCIE

摘要:

The novel hierarchical Ni-Co sulfide nanosheet-nanotubes arrays were directly grown on Ni foam, as binder-free electrodes, have been successfully synthesized following a one-step facile hydrothermal method combined with a sulfide treatment. The initial value of the area capacitance achieved 2.28 F cm(-2) at a current density of 1 mA cm(-2). A high areal capacitance retention of 95.2% compared to activation-induced peak value is achieved after 3000 charge-discharge cycles, which is much better than counter Ni-Co oxide electrode (1.75 F cm(-2) at 1 mA cm(-2), 93.2% retention compared to activation induced peak value). The outstanding and excellent super capacitive performance is ascribed to ion-exchange reaction, which induces a flexible hollow nanotube feature and show higher conductivity, compared with Ni-Co oxide NWs. Cyclic voltammetry (CV) and Electrochemical impedance spectra (EIS) results confirmed that the synthesized electrode contains the lowest resistance at high, and at lower frequency, leading to easy penetration of electrolytes and fast transportation of electrons inside the electrode. In this proposed work, a one-step hydrothermal method has been followed, and provided for the sulfide-induced, with a noticeable electrochemical performance of nickel cobaltite compounds and supplying a promising route for high-performance supercapacitor electrodes.

关键词:

nanotubes nickel foam cation exchange Ni-Co sulfide supercapacitors

作者机构:

  • [ 1 ] [Saddique, Jaffer]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 2 ] [Cheng, Xiaopeng]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 3 ] [Shi, Huifeng]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 4 ] [Wu, Rui]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China
  • [ 5 ] [Zhang, Yuefei]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

通讯作者信息:

  • 张跃飞

    [Zhang, Yuefei]Beijing Univ Technol, Inst Microstruct & Property Adv Mat, Beijing 100124, Peoples R China

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来源 :

APPLIED SCIENCES-BASEL

年份: 2019

期: 15

卷: 9

2 . 7 0 0

JCR@2022

ESI学科: ENGINEERING;

ESI高被引阀值:136

JCR分区:2

被引次数:

WoS核心集被引频次: 14

SCOPUS被引频次: 14

ESI高被引论文在榜: 0 展开所有

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