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摘要:
The effect of light-induced thermal annealing at low temperature on the structure and electronic properties of hydrogenated amorphous silicon (a-Si: H) as a function of annealing conditions was studied by FTIR spectra method. The deposition of a-Si: H films was performed by using microwave electron cyclotron resonance (MW ECR) plasma with the assistance of tungsten filament. In this study, the infrared spectroscopy results show the interesting changes under the different annealing condition. The increase in the transmission coefficient at both 630 and 2000 cm-1 indicates that bonded hydrogen moved and effused from the amorphous network. The bond-centered (BC) H diffusion model is used to explain the H elimination phenomenon, we argue that the BC H atoms formed by the nonradiative recombination of photo-induced carriers and the exchange between BC H and deeply trapped H produce more and more BC H atoms, the BC H atoms will recombine each other and form molecular hydrogen, the process of H elimination is prior to monohydride clustering and/or bonds switching.
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来源 :
Journal of Functional Materials
ISSN: 1001-9731
年份: 2005
期: 6
卷: 36
页码: 940-944