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作者:

Du, Gaoxiang (Du, Gaoxiang.) | Zheng, Shuilin (Zheng, Shuilin.) | Li, Yang (Li, Yang.)

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摘要:

Surface-modified ultra-fine brucite powder is a kind of environment-friendly fire-retardant of polymer. The ultra-fine brucite powder was surface-treated with two kinds of silane (A-174 and FR-693), and then filled into polypropylene (PP) as a kind of fire-retardant aimed. The effect of modification by silane on the properties of PP/brucite composite material was studied. The effect and modification mechanism were investigated by means of Fourier transfer infrared analysis, scanning electron microscopy of brucite powder and the fresh new surface of PP/brucite. The results show that the optimal dosage of brucite powder for silane A-174 and silane FR-693 is 1.5% and 1.0% in mass respectively and the temperature of surface treatment is 80°C. It indicates that the surface modification can enhance the izod impact strength of PP/Mg(OH)2 composite material by 0.3 kJ/m2, the bend modulus about 30%, and the retardant degree is enhanced to V-0 from V-1. The tensile strength of the composite material surface modified with silane FR-693 can be increased 1 MPa. The bending strength and elongation at break of the material are not improved by both silane.

关键词:

Bending strength Composite materials Dispersions Flame retardants Fourier transform infrared spectroscopy Hydrophobicity Mechanical properties Minerals Polypropylenes Silanes Surface treatment Tensile strength

作者机构:

  • [ 1 ] [Du, Gaoxiang]Department of Chemistry and Environment Engineering, China University of Mining and Technology, Beijing 100083, China
  • [ 2 ] [Zheng, Shuilin]Department of Chemistry and Environment Engineering, China University of Mining and Technology, Beijing 100083, China
  • [ 3 ] [Li, Yang]Beijing University of Technology, Beijing 100024, China

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来源 :

Journal of the Chinese Ceramic Society

ISSN: 0454-5648

年份: 2005

期: 5

卷: 33

页码: 659-664

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