As　a　new　type　of　unsaturated　linear　magnetoresistive　materials,　tungsten　ditelluride　series　material　has　potential　applications　in　the　fields　of　strong　magnetic　detection,　information　recording　and　magnetic　storage　devices.　The　current　development　concepts　of　＇green　materials＇,　＇green　chemical　technology＇　and　＇environmentally　friendly　technology＇　require　us　to　pursue　the　non-toxic,　low-emission　and　non-emission　in　material　synthesis　technology.　At　the　same　time,　the　prepared　products　show　excellent　performance　and　high　versatility　and　efficiency.　According　to　our　previous　work,　the　study　attempts　to　use　a　low-volatile　amine　solvent　as　a　pretreatment　raw　material　to　synthesize　a　tungsten　germanium-based　linear　magnetoresistive　material　by　hydrothermal/solvothermal　method　and　self-fluxing　method.　The　obtained　materials　were　subjected　to　XRD,　Raman,　SEM　and　Magnetoresistance.　Experimental　results　show　that　when　the　mass　ratio　of　W　and　Te　is　1:4,　the　prepared　material　is　pure　phase　and　the　sample　is　the　layered　structure.　The　Magnetoresistance　Property　points　out　that　the　maximum　value　is　about　190　%,　which　appears　in　the　condition　of　10　K　and　7　T.　Those　test　projects　include　phase,　structure　and　morphology　characteristics,　and　provide　technical　parameters　and　methods　for　the　development　of　green　synthesis　and　potential　applications　of　tungsten　ditelluride　series　linear　magnetoresistive　materials.　©　2020　Trans　Tech　Publications　Ltd,　Switzerland.