首页>成果

  • 综合
  • 标题
  • 关键词
  • 摘要
  • 学者
  • 期刊-刊名
  • 期刊-ISSN
  • 会议名称
搜索

[期刊论文]

Sn accommodation in tunable-void and porous graphene bumper for high-performance Li- and Na-ion storage

分享
编辑 删除 报错

作者:

Liu, Xiaoxu (Liu, Xiaoxu.) | Li, Na (Li, Na.) | Yang, Chen (Yang, Chen.) | 展开

收录:

EI Scopus SCIE

摘要:

Nanoscale microstructure designing is playing an important role in improving the performance of electrode materials of an electrochemical battery. The Sn based anode is among the very high-capacity but less-stable materials, and has been used mostly for anode of the Li-ion battery with unsatisfactory performance. In this work, we design a new type of 3D porous graphene and nano-Sn composite (Sn/ Void@G) by simple one-step annealing of graphene oxide, polystyrene spheres and stannic chloride for both high performance Li- and Na-ion battery anodes. More importantly, the 3D porous graphene formed tunable micro-nano void as a highly efficient "bumper" to accommodate the large volume expansion of nano-Sn particles. As results, the discharge specific capacity of the Sn/Void@G, anode still remains 45.3% while the charge-discharge current is increased 50 times, and the capacity is more than 400 mAh g(-1) after 500 cycles at 5C rate. For Na storage, the integrated anodes deliver the Na storage capacity of 786.1 mAh/g at 0.1C rate and the capacity of more than 340 mAh/g after 800 cycles at 2C rate. The present result on Li and Na ion battery may pave the way to next generation high power and energy density batteries. (C) 2019 Elsevier B.V. All rights reserved.

关键词:

Lithium ion battery Na-ion storage Sn anode High-performance 3D Porous graphene

作者机构:

  • [ 1 ] [Liu, Xiaoxu]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 2 ] [Feng, Yanqi]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 3 ] [Dong, Wanmeng]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 4 ] [Liu, Hui]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat I, Xian 710021, Shaanxi, Peoples R China
  • [ 5 ] [Liu, Shikun]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 6 ] [Zhao, Jiupeng]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 7 ] [Li, Yao]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China
  • [ 8 ] [Li, Na]Heilongjiang Univ Sci & Technol, Harbin 150027, Heilongjiang, Peoples R China
  • [ 9 ] [Yang, Chen]Heilongjiang Univ Sci & Technol, Harbin 150027, Heilongjiang, Peoples R China
  • [ 10 ] [Liu, Zhen]Tech Univ Clausthal, Inst Electrochem, Arnold Sommerfeld Str 6, D-38678 Clausthal Zellerfeld, Germany
  • [ 11 ] [Jia, Yanlin]Cent S Univ, Coll Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
  • [ 12 ] [Jia, Yanlin]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 13 ] [Li, Yao]Harbin Inst Technol, Ctr Composite Mat, Harbin 150001, Heilongjiang, Peoples R China

通讯作者信息:

  • [Zhao, Jiupeng]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China;;[Li, Yao]Harbin Inst Technol, Sch Chem Engn & Technol, Harbin 150001, Heilongjiang, Peoples R China;;[Jia, Yanlin]Cent S Univ, Coll Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China

查看成果更多字段

来源 :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

年份: 2019

卷: 790

页码: 1043-1050

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:211

JCR分区:2

被引次数:

WoS核心集被引频次: 21

SCOPUS被引频次: 23

近30日浏览量: 0

在线人数/总访问数:240/4516128
地址:北京工业大学图书馆(北京市朝阳区平乐园100号 邮编:100124) 联系我们:010-67392185
版权所有:北京工业大学图书馆 站点建设与维护:北京爱琴海乐之技术有限公司