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The morphology, composition, structure and formation mechanisms of precipitates in three Ni-base single crystal superalloys containing 3.2 at. % Ru by adding Cr (0 to 6.5 at. %) were investigated. The precipitation speed in the Low-Cr alloy was low at a temperature of 1100 °C. The ReRu-rich δ phase, with a hexagonal structure, was the primary phase. A high quantity of precipitates appeared in the high Cr alloy after 50 h of heat treatment. The quantity increased rapidly from that time. The σ phases dominated the precipitate after a short period of heating at 1100 °C, with the orientation relationship corresponding to [111] γ/γ′ // [111] σ and (110) γ/γ′ // (110) σ. The σ phase transformed into the intergrowth of the σ and the P phases discontinuously through the σ needle as the exposure time increased. The large elemental γ/γ′ partitioning ratio of Re in 6.5 at. % Cr was the key factor that promoted nucleation in the σ phase. © Published under licence by IOP Publishing Ltd.
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ISSN: 1757-8981
年份: 2019
期: 1
卷: 562
语种: 英文