Carbon　nanotubes　are　extensively　used　in　energy,　catalysis　and　environmental　fields　because　of　large　specific　area　and　superior　electrochemical　performances.　A　novel　CeO2-ZrO2/TiO2/CNT　anode　was　fabricated　through　sol-gel　method　to　improve　electrochemical　degradation　efficiency　towards　trace　pollutant　in　water　environment,　such　as　ceftazidime.　Surface　structure　and　elemental　compositions　were　characterized　by　scanning　electron　microscopy,　transmission　electron　microscopy,　X-ray　diffraction　and　X-ray　photoelectron　spectroscopy.　A　uniform　and　compact　loading　of　CeO2-ZrO2　and　TiO2　nanoparticles　were　observed　which　is　regarded　to　be　beneficial　for　stability　and　catalytic　improvement.　The　optimal　loading　amount　of　TiO2　and　CeO2-ZrO2　was　decided　by　electrochemical　performance　and　the　results　indicated　addition　of　6　mL　tetrabutyl　orthotitanate　in　0.5　g　CNT　and　3.33%　atomic　ratio　of　CeO2/C　resulted　in　a　highest　removal　rate　of　83.47%　under　3　mA.cm(-2).　Cyclic　voltammograms,　electrochemical　impedance　spectroscopy　and　hydroxyl　generation　test　were　conducted,　demonstrating　this　anode　displayed　superior　electrochemical　properties　with　greater　yield　of　center　dot　OH　and　lower　charge　transfer　resistance.　Moreover,　kinetic　parameters　were　optimized　in　this　study,　indicating　an　electrode　distance　of　2　cm　and　stirring　rate　of　400　rad.min(-1)　were　the　optimal　operation　condition　from　the　perspectives　of　energy　consumption　and　degradation　efficiency.　Finally,　the　degradation　intermediates　and　pathways　are　proposed　with　HPLC-MS.