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作者:

Wei, Qiumei (Wei, Qiumei.) | Zhu, Mankang (Zhu, Mankang.) | Zheng, Mupeng (Zheng, Mupeng.) | Hou, Yudong (Hou, Yudong.) (学者:侯育冬)

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EI Scopus SCIE

摘要:

A giant field-induced strain of 0.65% with excellent temperature insensitivity and fatigue resistance was achieved by introducing 1.5 mol.% B-site complex cations (Zn1/3Nb2/3)(4+) into the 0.93(Bi1/2Na 1/2)TiO3-0.07BaTiO(3) lead-free ferroelectric ceramics. (Bi1/2Na1/2)(0.93)Ba-0.07(Zn1/3Nb2/3)(x)Tit-xO(3) (0 <= x <= 0.025) ceramics were prepared by the columbite route, their microstructure, electric properties, and field-induced strain behavior were systematically investigated. XRD analysis reveals that the B-site substitution by complex cations (Zn1/3Nb2/3)(4+) induces the phase transition from R3c to pseudocubic structures, and demonstrates different phase evolution under field applied. At the composition x= 0.015, a composition-driven boundary between the nonergodic state and ergodic state is observed. Meanwhile, the substitution by complex cations (Zn1/3Nb2/3 )(4+) reduces the dimension of polar nanoregions (PNRs) due to the destruction of the long-range ferroelectric ordering. A phenomenological illustration based on Bokov's suggestion and Landau-Devenshire theory suggests the relationship between the size of PNRs and field-induced strain behavior. (C) 2018 Elsevier B.V. All rights reserved.

关键词:

Electroceramics Strain Phase transition Nanodomains Ferroelectric

作者机构:

  • [ 1 ] [Wei, Qiumei]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 2 ] [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 3 ] [Zheng, Mupeng]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China
  • [ 4 ] [Hou, Yudong]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

通讯作者信息:

  • [Zhu, Mankang]Beijing Univ Technol, Coll Mat Sci & Engn, Beijing 100124, Peoples R China

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来源 :

JOURNAL OF ALLOYS AND COMPOUNDS

ISSN: 0925-8388

年份: 2019

卷: 782

页码: 611-618

6 . 2 0 0

JCR@2022

ESI学科: MATERIALS SCIENCE;

ESI高被引阀值:211

JCR分区:2

被引次数:

WoS核心集被引频次: 43

SCOPUS被引频次: 43

ESI高被引论文在榜: 0 展开所有

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