Titanosilicate　ETS-4　with　the　Sr　and　Ni　cations　modification　were　prepared　by　hydrotherrmal　method　using　titanium　trichloride　and　tetraethoxysilane　as　raw　materials.　The　properties　and　morphology　of　the　materials　were　characterized　by　XRD,　SEM　techniques,　Sr　and　Ni　introduced　to　the　molecular　sieve　affected　the　frame　contraction　when　they　were　heated,　and　did　little　effect　on　the　crystallization　and　morphology.　N2　and　CH4　isotherms　of　each　sample　were　measured　at　room　temperature.　The　Sr　and　Ni　doping　could　improve　the　N2　and　CH4　adsorption　capacities　of　ETS-4.　The　capacities　of　the　two　gases　increased　in　the　pressurization　process　for　ETS-4-Sr　and　ETS-4-Ni,　with　the　pressure　increasing,　no　significant　change　in　capacities　of　N2　and　CH4　was　observed　over　the　ETS-4　sample.　Compared　to　ETS-4　molecular　sieves,　the　capacity　for　N2　of　ETS-4-Sr　and　ETS-4-Ni　at　the　pressure　of　1200　mmHg　increased　4.2　and　3.9　times,　respectively.　At　last,　the　results　indicated　that　the　cations　doping　(Sr2+　and　Ni2+)　can　improve　the　adsorption　performance　of　ETS-4　greatly.　©　(2013)　Trans　Tech　Publications,　Switzerland.